Physautotype

19th century printed reproduction of a still life believed to be a circa 1832 Niépce physautotype (glass original accidentally destroyed circa 1900)

The physautotype (from French) was a photographic process, invented in the course of his investigation of heliography, by Joseph Nicéphore Niépce and Louis Jacques Mandé Daguerre in 1832, in which images were produced by the use of lavender oil residue dissolved in alcohol as the photographic agent. The solution was coated onto a silver or glass plate and allowed to dry, after which it had a powdery white appearance. The plate was then exposed in a camera obscura for about 8 hours and developed with petroleum-based spirit vapors, which caused the least strongly exposed areas to become proportionally more transparent, creating a photographic image that was positive when viewed against a darker background.